1)cyclopropanation环丙烷化
1.Theoretical Studies on Reaction Pathways of Samarium(Ⅱ) Carbenoid-Promoteded Cyclopropanation Reaction of Ethylene;钐(Ⅱ)类卡宾CH_3SmCH_2X(X=Cl、Br和Ⅰ)促进乙烯环丙烷化反应途径的理论研究(英文)
2.Study on Cyclopropanation of Styrene Catalyzed by (μ_3-S)Fe_2CoCu(PPh_3)_2 (CO)_8;(μ_3-S)Fe_2CoCu(PPh_3)_2(CO)_8催化苯乙烯环丙烷化反应研究
3.Study on Asymmetric Cyclopropanation of 2,5 Dimethyl 2,4 hexadiene Catalyzed by Chiral Copper(Ⅱ) Complexes;手性铜络合物催化2,5-二甲基-2,4-己二烯不对称环丙烷化反应的研究(Ⅰ)
英文短句/例句
1.Cyclopropanation Reaction and Diastereoselectivity of Propargyl Sulfur Ylide with Acrylates炔丙型硫Ylide环丙烷化反应及其立体选择性
2.A Study of the Synthesis of Polysubstituted Cyclopropane;氯化钯催化下的烯键环丙烷化反应研究
3.Study of Trifluoromethylaion and Gem-Difluorocyclopropanation Reactions;三氟甲基化及二氟环丙烷化反应的研究
4.Studiy on the Synthesis of Polysubstituted Cyclopropane with Different Accelerater不同催化剂对烯键环丙烷化反应的影响
5.Study on the Synthesis of Cyclopropanes and Cyclopropenes;环丙烷和环丙烯类化合物的合成研究
6.The Research on Properties of the Catalyst in Preparation of Epichlorohydrin from Allyl Chloride by Epoxidation Method;氯丙烯环氧化法制环氧氯丙烷催化剂性能研究
7.Research on the Effect of Physical-Chemical and Biological Treatment Process of Epoxy Propane Wastewater with High Salinity;高盐环氧丙烷废水物化—生化处理研究
8.1- chloro -2,3-epoxypropane1-氯-2,3-环氧丙烷
9.Study on FeAl(PO_4)_2 Catalysts for 1,2-Dichloropropane to form Propylene Oxide in Membrane Reactor;1,2-二氯丙烷制环氧丙烷FeAl(PO_4)_2催化剂及膜催化反应的研究
10.Optimize Reaction Control to Improve ECH Yield优化反应控制 提高环氧氯丙烷收率
11.Theoretical Study on the Reaction of Chlorine Trifluoride with Propylene Oxide by Density Functional Theory三氟化氯和环氧丙烷反应的理论研究
12.Development of a new slag-free production process for epoxy propane无渣皂化生产环氧丙烷新技术的开发
13.Deal the polyester-cotton fabric with PECH-amine聚环氧氯丙烷胺化物对涤/棉的处理
14.POLYMERIZATION OF EPICHLOROHYDRIN BY YTTRIUM ACETYLACETONATE乙酰丙酮钇催化环氧氯丙烷的均聚合与共聚合
15.TECHNOLOGY REFORMATION AND EFFECT OF CYCLIZATION SYSTEM IN THE EPICHLOROHYDRIN PLANT环氧氯丙烷装置环化系统的改造及效果
16.Copolymerization of Propylene Oxide with Carbon Dioxide Catalyzed by Zn-Co Double Metal Cyanide ComplexesZn-Co DMC催化合成环氧丙烷-二氧化碳共聚物
17.Polymerization of Propylene Oxide by Using Multi-metal Cyanide Based Catalyst多金属氰化络合物催化环氧丙烷的聚合
18.liquefied propane gas tanker液化丙烷船液化丙烷运输船
相关短句/例句
cyclopropanation环丙烷化反应
1.Catalytic asymmetric cyclopropanation by chiral transition metal catalyst;手性过渡金属催化剂催化的不对称环丙烷化反应
2.The Relationshiop Between Bichiral Amino Alcohol(Salicylaldimino)Copper Complexes and Enantioselectivities of Cyclopropanation;双手性氨基醇水杨醛Schiff碱铜络合物构型与环丙烷化反应立体选择性的关系
3.Cyclopropanation Reaction and Diastereoselectivity of Propargyl Sulfur Ylide with Acrylates炔丙型硫Ylide环丙烷化反应及其立体选择性
3)aziridination氮杂环丙烷化
1.This review focuses on aziridine synthesis catalyzed by metal complex during the last twenty years, especially the progress of the catalytic aziridinations based on nitrene transfer to olefins or on carbene addition to imines.本文全面介绍了近 2 0年来的氮杂环丙烷的金属配合物催化合成 ,尤其是以氮宾转移到烯烃或碳宾加成到亚胺为合成途径的氮杂环丙烷化催化反应的研究进展 ,还包括该反应在金属催化时发生的竞争性插入到饱和C—H键的反应。
2.Catalytic aziridination and amidation reactions are two important reactions in organic synthesis and useful building blocks for organic synthesis, which make them attractive synthetic targets in their own right.催化氮杂环丙烷化及酰胺化反应是有机合成中的两类重要反应,是有机合成之砌块,其合成方法是重要的研究课题。
3.Recent progress in the application of selenonium and telluronium ylide in the stereoselective formation of three-membered ring compounds,such as cyclopropanation,epoxidation,and aziridination are summarized.概述了碲及硒叶立德在立体选择性小环化反应中的应用,包括环丙烷化反应、环氧化反应、氮杂环丙烷化反应等。
4)Asymmetric cyclopropanation不对称环丙烷化
1.Cu(Ⅱ) complexes of 1a~1c were applied to the asymmetric cyclopropanation of 1,1 diphenyl ethylene with alkyl diazoacetate.用手性α 氨基醇和原氯乙酸三乙酯作用得到的手性唑啉 2a~ 2c和 1,7 二氮 12 冠 4反应 ,合成了带手性侧链的1,7 二氮 12 冠 4衍生物 1a~ 1c ,并将其铜配合物运用于重氮醋酸酯对烯烃的不对称环丙烷化反
2.It was showed that the complex B has different catalytic performance in asymmetric cyclopropanation of styrene and DMHD (2,5 dimethyl 2,4 hexadiene) with diazoacetat.本文合成了一种新型的具有相对柔性手性环境的含C2对称轴的手性席夫碱化合物A ,并且初步考察了其铜配合物B在不对称环丙烷化反应中的催化性能 。
3.In this article, the progress on asymmetric cyclopropanation of olefins during the last decade was reviewed.本文从手性配体的发展出发 ,综述了烯烃不对称环丙烷化反应近 1 0年来的研究进展 ,对半咕啉、双唑啉等 C2 轴手性配体在该反应中的应用做了详细论述 ,介绍了反应机理研究的最新进展 ,并探讨了该反应在走向工业应用过程中所面临的主要问题。
5)ethylene oxide activation环氧丙烷活化
6)Epichlorohydrin activation环氧氯丙烷活化
延伸阅读
不对称环丙烷化分子式:CAS号:性质:不对称环丙烷及其衍生物的合成方法。 不对称加成反应 asymmetric addition reaction 以加成反应的方式进行不对称合成。例如应用光活性的均相催化剂对烯键进行催化加氢反应,可生成有旋光性的反应产物。
