硼氢化,hydroboration
1)hydroboration['haidr?u,b?:'rei??n]硼氢化
1.Malonyloxyborohydride,a hydroboration reagent,is prepared by reaction of malonic acid and sodium borohydride,and is used to react with dihydromyrcene in THF.用一种硼氢化试剂———丙二酸与硼氢化钠反应生成的丙二酰氧基硼氢化钠在THF中与二氢月桂烯反应制备香茅醇。
2.Numerous applications of FBS in hydroformylation, hydroboration and other organic reactions are also discussed.对氟两相体系在烯烃的氢甲酰化反应、硼氢化反应以及其它有机反应中的广泛应用作了讨论。
3.According to the result, the stereochemistry of this hydroboration and the configuration of diisocedrylborane were also confirmed.烯烃的硼氢化是一重要的有机反应。
英文短句/例句

1.Sodium metaborate is a by-product from deoxidation of sodium borohydride.偏硼酸钠是硼氢化钠的还原副产物。
2.Research on catalyst of hydrogen production from sodium borohydride in alkaline solution碱性硼氢化钠溶液析氢催化剂的研究
3.Study on Promotive Hydrolysis of Sodium Borohydride by Nickel Acetate醋酸镍促进硼氢化钠水解制氢的研究
4.Combination of sodium borohydride hydrogen generation system with PEM fuel cells硼氢化钠水解给PEMFC供氢的研究
5.Design of hydrogen generation systems for fuel cells by using hydrolysis of sodium borohydride基于硼氢化钠制氢燃料电池供氢系统设计
6.Preliminary Study on Electrochemical Reduction of Sodium Metaborate to Produce Sodium Borohydride;电化学还原偏硼酸钠制备硼氢化钠初探
7.The sodium borohydride can be obtained by deoxidation of the aforementioned sodium metaborate as raw material in the presence of metalic sodium and quartzite.以偏硼酸钠为原料,与金属钠、石英砂进行加氢反应来制备硼氢化钠。
8.Gravimetry for the Determination of Ru in Difficultly Dissolved Ru-B Solder Using NaBH_4-H_2 Reduction硼氢化钠-氢还原重量法测定难溶解钌-硼焊料中的钌
9.It is resistant to borohydride reduction in alcoholic solvents.在醇溶剂中,它不能被硼氢化物还原。
10.Study on the Method of Determining Content of Sodium Triacetoxy Borohydride;三乙酰氧基硼氢化钠测试方法的研究
11.Present studies on electron deficient borohydride and its ions缺电子硼氢化物及其离子的研究现状
12.A novel titanium-supported silver electrode for electrochemical oxidation of borohydride新型钛基银电极上硼氢化钠的电化学氧化
13.The Application of Asymmetric Hydoboration Based on α-Pinene;α-蒎烯类手性硼作用下的不对称硼氢化反应在有机合成中的应用
14.Kinetic performance of BH_4~- oxidation on Cu anode碱性溶液中硼氢化钠在铜阳极上的氧化行为
15.Sodium Borohydride Hydrolysis Catalyzed by Supportless Platinum-Ruthenium Alloys无载体铂钌合金催化水解硼氢化钠的研究
16.Preliminary Studies on Oxidation Kinetics of BH_4~- on Cu Anode in an Alkaline Solution碱性介质中硼氢化物铜阳极氧化动力学初探
17.Sodium Borohydride Hydrolysis Generate Hydrogen-the Small Proton Exchange Membrane Fuel Cell Integration Research硼氢化钠水解制氢—小型质子交换膜燃料电池一体化研究
18.Ring-opening Polymerization of Cyclohexene Oxide by Rare Earth Borohydrides稀土硼氢化合物对环氧环己烷的开环聚合
相关短句/例句

borohydride[,b?:r?'haidraid]硼氢化
1.Electroless gold plating baths using borohydride as reducing agent are studied.研究了以硼氢化物作为还原剂的化学镀金溶液,通过正交实验得出了主盐、还原剂、络合剂、pH值和温度对镀速影响的关系,对正文实验结果进行线性回归,得出了化学镀金动力学经验方程,并得出最佳配方及工艺条件。
2.A polymeric borohydride anion reducing reagent(BER)was preparedfromhome-made 7ll # strong basic anion-exchange resin and potassium borohydride,The BER has a ca-pacity of.氯型季铵盐型强碱性阴离子交换树脂711#与硼氢化钾反应制得聚合物硼氢阴离子还原剂,树脂容量3。
3)lithium borohydride硼氢化锂
1.Firstly,3,4,5-tris(n-dodecan-1-yloxy)benzyl alcohol was synthesized by the alkylation of methyl-3,4,5-trihydroxylbenzoate with 1-bromododecane,followed by the reduction of 3,4,5-tris(n-dodecan-1-yloxy)benzoate with lithium borohydride;then 3,4,5-tris(n-dodecan-1-yloxy)benzyl aldehyde was obtained through oxidation of 3,4,5-tris(n-dodecan-1-yloxy)benzy.以没食子酸甲酯为原料,与1-溴代十二烷醚化生成3,4,5-三-(十二烷氧基)苯甲酸甲酯,然后采用原位生成的硼氢化锂还原成3,4,5-三-(十二烷氧基)苯甲醇,再用氯铬酸吡啶盐(PCC)氧化成3,4,5-三-(十二烷氧基)苯甲醛,最后与巴比妥酸进行Knoevenagel缩合反应得到了标题化合物。
2.3,5Dihydroxybenzyl alcohol is synthesized from 3,5dihydroxybenzoic acid by improved esterification,acylation and reduction by lithium borohydride,the total yield is 75%,which gives a convenient synthetic method.以3,5二羟基苯甲酸为原料,经酯化、酰化、硼氢化锂还原等改进步骤合成了3,5二羟基苯甲醇,总收率达75%,提供了一条较为简便的适合于工业化生产的合成方法。
3.Recently,lithium borohydride(LiBH_4) and other related complex metal hydrides have attracted ever-increasing attention as potential high-capacity hydrogen storage media.近年来,随着储氢材料领域的不断拓展,以硼氢化锂(LiBH4)为典型代表的高储量配位金属氢化物日渐成为新兴的储氢材料研究热点。
4)sodium borohydride硼氢化钠
1.Research on synthesis and hydrolysis of sodium borohydride;硼氢化钠的制备方法及水解制氢
2.Platinum-based catalysts for hydrogen generation from hydrolysis of sodium borohydride;硼氢化钠水解制氢用铂基催化剂的研究
3.Determination of Mercury in Battery by Sodium Borohydride Reduction-Non-Dispersive Atomic Fluorescence Spectrometry;硼氢化钠还原-无色散原子荧光法测定电池中汞
5)potassium borohydride硼氢化钾
1.Determination of Mercury in Coatings of Indoor Decorating and Refurbishing Materials by Potassium Borohydride Reduction-Atomic Fluorescence Spectrometry;硼氢化钾还原-原子荧光光谱法测定室内装饰装修用涂料中汞
2.In this paper,various of modified potassium borohydride systems were studied in the reduction of p-hydroxyphenylacetate methyl.研究了硼氢化钾系列的多种还原体系将对羟基苯乙酸甲酯还原为对羟基苯乙醇的反应。
3.The effect of potassium borohydride on ester and carboxylic acid reduction was introduced.研究了硼氢化钾对酯和羧酸的还原作用。
6)KBH_4硼氢化钾
1.Spectrophotometric determination of silicon in steel by forming silicomolybdenum blue complex with KBH_4 as reducing reagent;硼氢化钾还原-硅钼蓝分光光度法测定钢铁中硅
延伸阅读

就地硼氢化分子式:CAS号:性质: 在有机合成和药物合成中,将反应物与硼氢化钠(钾)一同置于反应器中,再滴入三氟化硼乙醚液,就地发生硼烷,就地进行硼氢化。这样就省去了硼烷的吸收步骤,使操作大为简化,适于大量制备和工业生产。