胺基化,amination
1)amination胺基化
1.2-(N,N-biscarboxymethyl)aminomethyl-6-benzoyl-4-methylphenol was synthesized from 4-methylphenol through a sequence of reaction, esterfication by benzoyl chloride, Fries rearrangement catalyzed by AlCl_3 without any solvent, chloromethylation by formaldehyde and concentrated HCl, amination by diethyl iminodiacetate using TEA as a proton absorbent, hydrolysis by Ba(OH)_2 solution. 以对甲酚为原料,在无溶剂、无AlCl3催化条件下利用Fries重排、氯甲基化、胺基化、水解等反应合成2 (N,N 二羧甲基)氨甲基 6 苯甲酰基 4 甲基苯酚。
2.2,6,6-Trimethyl-2-cyclohexen-1-aldehyde was prepared from citral undergo amination, cyclization and hydrolysis reaction, mechanics of the reactions is analysed, product content greater than 97%, yield is 86.以柠檬醛为原料,经胺基化,环化,水解三步反应得到2,6,6-三甲基-2-环己烯-1-甲醛,含量97%以上,产率86。
英文短句/例句

1.Adsorption behavior of aminated polymeric resin for adsorptingp-methylaniline from aqueous solution胺基化树脂对水溶液中对甲苯胺的吸附性能
2.Study on Synthesis of Para-Isopropylaniline by Alkylation of Aniline;苯胺烷基化合成对异丙基苯胺的研究
3.octadecyl dimethyl amine oxide十八烷基二甲基氧化胺
4.hexadecyl tributyl ammonium bromide十六烷基三丁基溴化胺
5.methoxymethylated polyamide甲氧基甲基化聚酰胺
6.Synthesis of Nitroaniline and Derivants by Vicarious Nucleophilic Substitution of Hydrogen;VNS胺化法合成硝基苯胺及其衍生物
7.Synthesis of Anthranilic Diamide Derivatives邻甲酰胺基苯甲酰胺类化合物的合成
8.trimethylammoniumchloride acetate氯化三甲基胺醋酸盐
9.partially aromatic polyamide fibre部分芳基化聚酰胺纤维
10.Alkyl dimethylamine is made from fatly alcohol and dimethyla-mine by one stage catalysis.由脂肪醇、甲胺一步催化法制取烷基二甲基胺。
11.edrophonium chloride氯化乙基(3-羟苯基)二甲胺;氯化滕西隆
12.Study on the Catalytic Direct Amination of Toluene to Toluidine;甲苯直接催化氨基化制甲基苯胺研究
13.tetradecyl benzyl dimethyl ammonium chloride十四烷基二甲基苄基氯化胺
14.Any of various chemical compounds containing two amino groups, especially hydrazine.二胺,联胺含有两个氨基的化合物,特别是联氨
15.An organic compound, such as acetamide, containing the CONH2 radical.醯胺一种有机化合物,如乙醯胺,含有CONH2基
16.Optimization of Fermentation Medium of Microbial Transglutaminase;微生物谷氨酰胺转胺酶发酵培养基的优化
17.Synthesis of N, N-Dimethylcyclohexanamine with Cyclohexane and Methanol;环己胺与甲醇催化合成N,N-二甲基环己胺
18.Development of Monoalkyl Dimethyl Tertiary Amine Production Process by Aminating Fatty Alcohol under Atmospheric Pressure;脂肪醇常压胺化法制单烷基叔胺工艺开发
相关短句/例句

N-alklation胺烷基化
1.Methods: Starting from styrene oxide,N-methylethanolamine and 2aminonicotinic acid,the target compound was synthesized via 6 reactive steps involving nucleophilic ring-opening,chlorination,alkalinization,reduction,N-alklation and cyclization.方法:以N-甲基乙醇胺、氧化苯乙烯和2-氨基烟酸为原料,经亲核开环、氯代、碱化、还原、胺烷基化和环合6步制得了抗抑郁药米氮平。
3)aminomethylation[,?min?u,meθi'lei??n]胺甲基化
1.Study on the modification of aminomethylation of partially hydrolyzed PAM and Its application in sugar manufacture;部分水解的聚丙烯酰胺的胺甲基化改性及其在制糖应用研究
2.After aminomethylation reaction,non-alpha-tocopherols aminomethylated products were extracted by solvent.对原料进行胺甲基化反应后,用溶剂萃取非α-生育酚胺甲基化产物。
4)Amidocarbonylation胺基羰基化
1.Study on the Catalysis of Cobalt-Phosphines for Paraformaldehyde Amidocarbonylation;钴-膦配合物催化多聚甲醛胺基羰基化反应的研究
5)amino functionalization胺基官能化
6)isobutylamination异丁基胺化
1.Amprenavir in overall yield of 73% was obtained from(2S,3S)-3-(t-butoxy)-amido-1,2-epoxy-4-phenylbutane via isobutylamination,N-4-nitrobenzene sulfonylation,reduction,deprotection,and then condensation with 7.以(2S,3S)-1,2-环氧基-3-叔丁氧酰胺基-4-苯丁烷为原料,经过异丁基胺化、N-对硝基苯磺酰化、还原、脱保护后再与(S)-3-羟基四氢呋喃-琥珀酰亚胺基碳酸酯(7)缩合制得安普那韦,总收率73%,其结构经1H NMR和MS确证。
延伸阅读

酰基酰胺基化反应分子式:CAS号:性质:烯烃用四氟化酰基硼和腈处理,在烯键上引入酰基和酰胺基,生成。此加成反应遵守马尔科夫尼科夫规则,亲电的酰基进入到氢原子较多的烯键碳原子上。