1,3-环己二酮,1,3-Cyclohexanedione
1)1,3-Cyclohexanedione1,3-环己二酮
1.Reaction of Aromatic Aldelyde with 1,3-Cyclohexanedione Catalyzed by Acidic Ionic Liquid;酸性离子液体催化芳香醛与1,3-环己二酮类衍生物的反应
2.Preparation of 2,2′-Methylenebis(1,3-cyclohexanedione);2,2′-亚甲基双(1,3-环己二酮)的制备
3.With 4-mesyl-2-nitro-benzoyl chloride and 1,3-cyclohexanedione as the primary materials,enol ester was synthesized as a primary intermediate under basic conditions, and then transformed to 2-(4′-mesyl-2′-nitro-benzoyl)-cyclohexane-1,3-dione through catalytic rearrangement.以2-硝基-4-甲磺酰基-笨甲酰氯和1,3-环己二酮为原料,首先碱性条件下合成烯醇酯,然后再经催化重排制得甲基磺酮,讨论了反应条件对产品收率的影响并得到了适宜的工艺条件。
英文短句/例句

1.Reaction of Aromatic Aldehydes with 5,5-Dimethyl-1,3-cyclohexandione in Water Catalyzed by Functionalized Ionic Liquid功能离子液体水相催化芳醛与5,5-二甲基-1,3-环己二酮的反应
2.Reaction of Aromatic Aldelyde with 1,3-Cyclohexanedione Catalyzed by Acidic Ionic Liquid;酸性离子液体催化芳香醛与1,3-环己二酮类衍生物的反应
3.Synthesis of Acridine Derivatives Using the Reaction of 5,5-Dimethylcyclohexane-1,3-dione and N-Benzylideneaniline in Ionic Liquid离子液体中5,5-二甲基-1,3-环己二酮与N-芳亚甲基芳胺反应合成吖啶衍生物
4.Study on Catalytic Synthesis of Cyciohexanone 1,3-butanediol Ketal by Sulfamic Acid;氨基磺酸催化合成环己酮1,3-丁二醇缩酮
5.4-Dimethylaminopyridine-Catalyzed Benzannulation Reaction of Aromatic 1,3-Diketones with 3-Butyn-2-one4-二甲氨基吡啶催化的1,3-二酮与3-丁炔-2-酮的苯环化反应
6.Synthesis of the Conjugated Ketene Dithioacetals by 2-(1,3-Dithiopropylene)Methylene Aliphatic Ketone由2-(1,3-亚丙二硫基)亚甲基脂环酮出发合成共轭的烯酮硫缩醛
7.Reactions of 2,2-Pentamethylene-1,3-dioxan-4,6-dione with Triethyl Orthoformate and Aromatic Amines2,2-亚戊基-1,3-二氧六环-4,6-二酮与原甲酸三乙酯和芳香胺的反应
8.Synthesis of 4,5-di-(p-chloride benzylthio)-1,3-dithiole-2-thione Ligand and Identify the Structure4,5-二对氯苄硫基-1,3-二硫杂环戊烯-2-硫酮配体的合成及其结构表征
9.Synthesis and Properties of Disodium (2-Undecyl-1,3-Dioxane-5,5-Diyl)-Dicarboxylate;2-正十一烷基-1,3-二氧杂环己烷-5,5-二羧酸二钠盐的合成和性质
10.Synthesis of 1,4-Di(5,5-bismethyl-1,3-oxy-2-phosphacyclohexyl-phosphacyl) piperazine1,4-二(5,5-二甲基-1,3-二氧-2-磷环己基膦酰基)哌嗪的合成研究
11.Thioacetalization Reaction of 1-(1,3-Dithian-2-ylidene)propan-2-one as 1,3-Propandithiol Equivalent1,3-丙二硫醇替代试剂1-(1,3-二噻-2-亚基)丙酮的缩硫醛/酮化反应
12.Catalytic Synthesis of Cyclohexanon 1,2-Propanediol Ketal环己酮1,2-丙二醇缩酮的催化合成
13.Study on Solubilities of Succinic Acid in Cyclohexane,Cyclohexanone and Cyclohexanol丁二酸在环己烷,环己酮,环己醇中溶解度的研究
14.Progress in synthesis of dihydroxyacetone from glycerol由甘油制备1,3-二羟基丙酮的研究进展
15.Preparation of 1,3-dimethyl-2-imidazolidinone1,3-二甲基-2-咪唑啉酮的制备
16.Synthesis of Bis-thiazolidinone Derivatives by 1,3-Dipolar Cycloaddition1,3-偶极环加成合成双-噻唑啉酮衍生物
17.Study of Separation for the Binary Systems of Cyclohexanol and Cyclohexanone by Extraction Rectification;环己醇与环己酮二元体系萃取精馏分离研究
18.Recyclable SiO_2-Supported CeCl_3·7H_2O-NaI Catalyzed Alkylation of 1,3-Dicarbonyl Compounds under Solvent-Free Conditions可循环利用硅胶吸附三氯化铈-碘化钠催化1,3-二酮的烷基化无溶剂反应
相关短句/例句

2-cyclohexanone-1,3-dioxime2-环己酮-1,3-二肟
3)1,3-Cyclohexanediono and formaldehyde1,3-环己二酮-甲醛
4)cyclohexanone 1,3-propanediol ketal环己酮1,3-丙二醇缩酮
1.The cyclohexanone 1,3-propanediol ketal is synthesized from cyclohexanone and 1,3-propanediol in the presence of SO~(2-)_4-TiO_2/Al_2O_3 solid superacid catalyst.以SO42--TiO2/A l2O3固体超强酸催化剂,通过环己酮和1,3-丙二醇的缩合反应,研究合成了环己酮1,3-丙二醇缩酮,较系统地研究了催化剂的活化温度、TiO2的负载量、催化剂用量、反应物配比、带水剂对缩合反应的影响。
5)cyclohexanone 1,3-butanediol ketal环己酮1,3-丁二醇缩酮
6)5,5-dimethyl-1,3-cyclohexanedione5,5-二甲基-1,3-环己二酮
1.A novel synthesis of 3,3,6,6-tetramethyl-9-aryl-1,2,3,4,5,6,7,8-octahydroxanthene-1,8-dione via condensation of aromatic aldehydes with 5,5-dimethyl-1,3-cyclohexanedione using expansible graphite as catalyst was described.在可膨胀石墨催化下,由芳香醛和5,5-二甲基-1,3-环己二酮缩合制备了3,3,6,6-四甲基-9-芳基-1,2,3,4,5,6,7,8-八氢化氧杂蒽-1,8-二酮。
2.The 4-(3-chlorophenyl)-7,7-dimethyl-5-oxo-3,4,5,6,7,8-hexahydrocoumarin was synthesized from 3-chlorobenzaldehyde,5,5-dimethyl-1,3-cyclohexanedione and isopropylidene malonate catalyzed by tetrabutylammonium bromide in aqueous medium.研究了四丁基溴化铵(TBAB)催化下的水介质中,3-氯苯甲醛、丙二酸亚异丙酯和5,5-二甲基-1,3-环己二酮三组分缩合,一步合成系列7,7-二甲基-4-(3-氯苯基)-5-氧代-3,4,5,6,7,8-六氢香豆素。
3.The reaction of substituted cinnamonitriles with 5,5-dimethyl-1,3-cyclohexanedione in 95% ethanol catalyzed by KF-montmorillonite, provides a fast, efficient and high-yielding access to 2-amino-3-cyano-4-aryl-7,7-dimethyl-5-oxo-4H-5,6,7,8-tetrahydrobenzo[b]pyran.以KF-蒙脱土为催化剂,取代肉桂腈与5,5-二甲基-1,3-环己二酮在95%乙醇中回流反应得2-氨基-3-氰基-4-芳基-7,7-二甲基-5-氧代-4H-5,6,7,8-四氢苯并[b]吡喃,此方法快速、方便、高效,同时考察了溶剂、催化剂对反应的影响。
延伸阅读

1,3-环己二酮分子式:C6H8O2分子量:112.13CAS号:504-02-9性质:棱状晶体。熔点105-106℃。溶于水、乙醇、丙酮、氯仿、沸苯,微溶于乙醚、二硫化碳。制备方法:将间苯二酚与氢氧化钠溶液投入压热釜,加入镍催化剂,在50℃、70-100大气压通氢反应10-12h。然后降温、泄压,滤除催化剂,滤液用浓盐酸酸化,冷至0℃,滤出结晶,即1,3-环己二酮粗品。粗品用热苯重结晶,得成品。用途:用于有机合成。